Pengembangan Produk Olesan Menggunakan Oleogel Minyak Sawit Merah sebagai Pensubstitusi Lemak Padat

Annisa Noor Rachmawati, Nur Wulandari, Eko Hari Purnomo

Abstract

Red palm oil (RPO) is a derivative product of crude palm oil rich in carotenoids, which can be developed into food products as a source of provitamin A. Although RPO is liquid at room temperature, it is often applied in the form of solid fat, generally through the addition of solid fat fractions containing a large quantity of saturated fatty acids. Therefore, RPO must be modified to turn it into solid at room temperature without changing its fatty acid composition, resulting in RPO oleogel. This study aimed to obtain a spread product formula using RPO oleogel made with beeswax oleogelator to substitute stearin and to characterize the quality of the spread product. The research consisted of two main stages, namely formulation and characterization of RPO oleogel and spread product samples. As a result, oleogelation increased the RPO resistance to temperature changes. Moreover, RPO slip melting point increased from 16.33±0.58–18.00±0.00 to 38.00±0.00–39.33±0.58 °C when it became RPO oleogel. RPO oleogel, which is substituted in spread products, produced higher total carotenoids and spreadability compared to spread products with stearin as a raw material. The hedonic sensory test showed that the most preferred product was 60% RPO oleogel substitution, resulting in spreadability of 285.0±0.6 mm/min, despite not significantly different from commercial one (257.4±3.0 mm/min) and carotenoid content of 462.93±10.32 ppm. However, the taste attribute of the selected spread product still needs to be improved (acceptance score 3.65±1.31 from a maximum score of 7).

References

Abdolmaleki, K., Alizadeh, L., Nayebzaedh, K., Baranowska, H. M., Kowalsczewski, P. L., & Khaneghah, A. M. (2022). Potential application of hydrocolloid-based oleogel and beeswax oleogel as partial substitutes of solid fat in margarine. Applied Sciences, 12(23), 1–13. https://doi.org/10.3390/app122312136

Amevor, P. M., Laryea, D., & Barimah, J. (2018). Sensory evaluation, nutrient composition and microbial load of cashew nut–chocolate spread. Cogent Food & Agriculture, 4(1), 1–10. https://doi.org/10.1080/23311932.2018.1480180

[AOCS] American Oil Chemists' Society. (2009). AOCS Official Method Cc 3-25 Slip Melting Point.

[AOCS] American Oil Chemists' Society. (2022). AOCS Official Method Cd 16b-93 Solid Fat Content (SFC) by Low-Resolution Nuclear Magnetic Resonance, Direct Method.

Board, P. W., Aichen, K., & Kuskis A. (2007). Measurement of the spreadability of margarine and butter using a single pin maturometer. International Journal of Food Science & Technology, 15(3), 277–283. https://doi.org/10.1111/j.1365-2621.1980.tb00940.x

[BPOM] Badan Pengawas Obat dan Makanan. (2019). Peraturan Badan Pengawas Obat dan Makanan Nomor 11 Tahun 2019 tentang Bahan Tambahan Pangan. Badan Pengawas Obat dan Makanan, Jakarta.

[BPS] Badan Pusat Statistik. (2022). Profil anak usia dini. https://www.bps.go.id/publication/2022/12/13/dea4ac1faa8b3e121c9fb925/profil-anak-usia-dini-2022.html [16 November 2023].

[BSN] Badan Standardisasi Nasional. 2006. Standar Nasional Indonesia tentang Minyak Kelapa Sawit Mentah (Crude Palm Oil) (SNI 01-2902-2006). Badan Standardisasi Nasional, Jakarta.

Chiu, S., Williams, P. T., & Krauss, R. M. (2017). Effects of a very high saturated fat diet on LDL particles in adults with atherogenic dyslipidemia: A randomized controlled trial. PLoS ONE, 12, 1–14. https://doi.org/10.1371/journal.pone.0170664

Dewi, E. K., Mardawati, E., & Nurhasanah, S. (2023). Evaluasi perubahan warna dalam tahapan pengolahan minyak mentah sawit menjadi minyak sawit merah dan minyak goreng sawit sebagai indikator kandungan β-karoten minyak. Biomass, Biorefinery, and Bioeconomy, 1, 25–29.

Dian, N. L. H. M., Hamid, R. A., Kanagratnam, S., Isa, W. R. A., Hassim, N. A. M., Ismail, N. H., Omar, Z., & Sahri, M. M. (2017). Palm oil and palm kernel oil: Versatile ingredients for food applications. Journal of Oil Palm Research, 29(4), 487–511. https://doi.org/10.21894/jopr.2017.00014

Doan, C. D., de Wall, D. V., Dewettick, K., & Patel, A. R. (2015). Evaluating the oil-gelling properties of natural waxes in rice bran oil: Rheological, thermal, and microstructural study. Journal of the American Oil Chemists' Society, 92(6), 801–811. https://doi.org/10.1007/s11746-015-2645-0

Espert, M., Sanz, T., & Salvador, A. (2020). Use of milk fat/cellulose ether emulsions in spreadable creams and the effect of in vitro digestion on texture and fat digestibility. Foods, 9(6), 1–8. https://doi.org/10.3390/foods9060796

Eze, S. O., Orji, J. N., Okechukwu, V. U., Omokpariola, D. O., Umeh, T. C., & Oze, N. R. (2021). Effect of processing method on carotenoid profiles of oils from three varieties of Nigerian palm oil (Elaeis guineensis). Journal of Biophysical Chemistry, 12(3), 23–31. https://doi.org/10.4236/jbpc.2021.123003

Flöter, E., Wettlaufer, T., Conty, V., & Scharfe, M. (2021). Oleogels: Their applicability and methods of characterization. Molecules, 26(6), 1–19. https://doi.org/10.3390/molecules26061673

Gratzer, K., Susilo, F., Purnomo, D., Fiedler, S & Brodschneider, R. (2019). Autochthonous and introduced bees: Challenges for beekeeping in Indonesia with autochthonous and introduced bees. Bee World, 96(2), 40–44. https://doi.org/10.1080/0005772X.2019.1571211

Gurning, M., Hukom, E. H., & Latusia, F. (2022). Dukungan keluarga dan sumber informasi terhadap pemberian vitamin A pada balita. Jurnal Keperawatan, 14(2), 427–432.

Han, W., Chai, X., Liu, Y., Xu, Y., & Tan, C. P. (2022). Crystal network structure and stability of beeswax-based oleogels with different polyunsaturated fatty acid oils. Food Chemistry, 381, 1–11. https://doi.org/10.1016/j.foodchem.2021.131745

Harianti, R., Marliyati, S. A., Rimbawan, & Sukandar, D. (2018). Development of high antioxidant red palm oil cake as a potential functional food. Jurnal Gizi Pangan, 13(2), 63–70. https://doi.org/10.25182/jgp.2018.13.2.63-70

Hasibuan, H. A., Akram, A., Putri, P., Mentari, E. C., & Rangkuti, B. T. (2018). Pembuatan margarin dan baking shortening berbasis minyak sawit merah dan aplikasinya dalam produk bakery. Agritech, 38(4), 353–363.

Hassim, N. A. M., Kanagaratnam, S., Ismail, N. H., Dian, N. L. H. M., Isa, W. R. A., & Seng, N. S. S. (2021). Palm-based chocolate spread for wide range temperature applications using sunflower wax, carnauba wax, and beeswax. Journal of Oil Palm Research, 34(3), 535–545. https://doi.org/10.21894/jopr.2021.0051

Helwani, Z., Zahrina, I., Tanius, N., Fitri, D. A., Tantino, P., Muslem, M., Othman, M. R., & Idroes, R. (2021). Polyunsaturated fatty acid fractionation from crude palm. Processes, 9(12), 1–10. https://doi.org/10.3390/pr9122183

Hermanns, A. S., Zhou, X., Xu, Q., Tadmor, Y., & Li, L. (2020). Carotenoid pigment accumulation in horticultural plants. Horticultural Plant Journal, 6(6), 343–360. https://doi.org/10.1016/j.hpj.2020.10.002

Huang, Y., Liu, C., Huang, F., Zhou, Q., Zheng, C., Liu, R., & Huang, J. (2022). Quality evaluation of oil by cold-pressed peanut from different growing regions in China. Food Science & Nutrition, 10(6), 1975–1987. https://doi.org/10.1002/fsn3.2813

Ismail, A. H., Wongsakul, S., Ismail-Fitry, M. R., Rozzamri, A., & Mat Yusoff, M. (2020). Physical properties and sensory acceptance of red palm olein-based low-fat ice cream added with guar gum and xanthan gum as stabilizers. Food Research, 4(6), 2073–2081. https://doi.org/10.26656/fr.2017.4(6).229

Jeyakodi, S., Krishnakumar, A., & Chellappan. D. K. (2018). Beta carotene - therapeutic potential and strategies to enhance its bioavailability. Nutritional Food Science International Journal, 7(4), 1–7. https://doi.org/10.19080/NFSIJ.2018.07.555716

[Kemenkes] Kementerian Kesehatan. (2014). Peraturan Menteri Kesehatan RI Nomor 32 Tahun 2014 tentang Upaya Perbaikan Gizi. Kementerian Kesehatan, Jakarta.

[Kemenkes] Kementerian Kesehatan. (2019). Laporan Nasional Riset Kesehatan Dasar 2018. Lembaga Penerbit Badan Penelitian dan Pengembangan Kesehatan, Jakarta.

[Kemenkes] Kementerian Kesehatan. (2019). Peraturan Menteri Kesehatan Nomor 28 Tahun 2019 tentang Angka Kecukupan Gizi yang Dianjurkan untuk Masyarakat Indonesia. Kementerian Kesehatan, Jakarta.

Kovács, A., Körmendi, L., Kerti, K. B. (2021). Palm oil substitution in hazelnut spread. Progress in Agricultural Engineering Sciences, 17(S1), 111–117. https://doi.org/10.1556/446.2021.30013

Latha, R. B., & Nasirullah, D. R. (2014). Physico-chemical changes in rice bran oil during heating at frying temperature. Journal of Food Science and Technology, 51, 353–340. https://doi.org/10.1007/s13197-011-0495-9

Lioe, H. N., Fadhilah, A., & Istiqamah. (2020). Formulasi campuran bahan pengemulsi untuk bolu sponge. Jurnal Mutu Pangan : Indonesian Journal of Food Quality, 7(1), 7–13. https://doi.org/10.29244/jmpi.2020.7.1.7

Liu, L., Feng, S., Chen, T., Zhou, L., Yuan, M., Liao, J., Huang, Y., Yang, H., Yang, R., & Ding, C. (2021). Quality assessment of Camellia oleifera oil cultivated in Southwest China. Separations, 8(9), 144. https://doi.org/10.3390/separations8090144

Maryuningsih, R. D., Nurtama, B., & Wulandari, N. (2021). Pemanfaatan karotenoid minyak sawit merah untuk mendukung penanggulangan masalah kekurangan vitamin A di Indoensia. Jurnal Pangan, 30(1), 65–74.

Meilgaard, M., Civille, G., & Carr, B. T. 2007. Sensory Evaluation Technique (Ed ke-4). CRC Press, New York.

Morcillo, F., Vaissayre, V., Serret, J., Avallone, S., Domonhédo, H., Jacob, F., & Dussert, S. (2021). Natural diversity in the carotene, tocochromanol, and fatty acid composition of crude palm oil. Food Chemistry, 365, 1–10. https://doi.org/10.1016/j.foodchem.2021.130638

Morenga, L. T., & Montez, J. M. (2017). Health effects of saturated and trans-fatty acid intake in children and adolescents: A systematic review and meta-analysis. PLoS ONE, 12(2), 1–20. https://doi.org/10.1371/journal.pone.0186672

Mudgil, D., & Barak, S. (2020). Development and characterization of novel spreadable dairy butter via incorporation of low-melting point fat from ghee. Biointerface Research in Applied Chemistry, 10(4), 5755–5759. https://doi.org/10.33263/BRIAC104.755759

Ng, M. H., & Choo, Y. M. (2016). Improved method for the qualitative analyses of palm oil carotenes using UPLC. Journal of Chromatographic Science, 54(6), 633–638. https://doi.org/10.1093/chromsci/bmv241

Olanrewaju, A. S., & Moriyike, O. E. (2013). Physicochemical characteristics and the effect of packaging materials on the storage stability of selected cucurbits oils. American Journal of Food and Nutrition, 1(3), 34–37. https://doi.org/10.12691/ajfn-1-3-3

Pang, M., Shi, Z., Lei, Z., Ge, Y., Jiang, S., & Cao, L. (2020). Structure and thermal properties of beeswax-based oleogels with different types of vegetable oil. Grasas y Aceites, 71(1), 1–11. https://doi.org/10.3989/GYA.0806192

Patel, A. R., Cludts, N., Sintang, M. D., Lesaffer, A., & Dewettinck, K. (2014). Edible oleogels based on water soluble food polymers: Preparation, characterization, and potential application. Food & Function, 5(11), 2833–2841. https://doi.org/10.1039/c4fo00624k

Patel, A. R., Babaahmadi, M., Lesaffer, A., & Dewettinck, K. (2015). Rheological profiling of organogels prepared at critical gelling concentrations of natural waxes in a triacylglycerol solvent. Journal of Agricultural and Food Chemistry, 63(17), 4862–4869. https://doi.org/10.1021/acs.jafc.5b01548

Patel, A. R., & Dewettinck, K. (2016). Edible oil structuring: An overview and recent updates. Food & Function, 7(1), 20–29. https://doi.org/10.1039/c5fo01006c

Pehlivanoğlu, H., Demirci, M., Toker, O., Konar, N., Karasu, S., & Sagdic, O. (2017). Oleogels, a promising structured oil for decreasing saturated fatty acid concentrations: Production and food-based applications. Critical Reviews in Food Science and Nutrition, 58(8), 1330–1341. https://doi.org/10.1080/10408398.2016.1256866

Pérez-Monterroza, E. J., Márquez-Cardozo, C. J., & Ciro-Velásquez, H. J. (2014). Rheological behavior of avocado (Persea americana Mill, cv. Hass) oleogels considering the combined effect of structuring agents. Food Science and Technology, 59, 673–679. https://doi.org/10.1016/j.lwt.2014.07.020

Pipoyan, D., Stepanyan, S., Seda, S., Beglaryan, M., Costantini, L., Molinari, R., & Merendino, N. (2021). The effect of trans fatty acids on human health: Regulation and consumption patterns. Foods, 10(10), 2452–2475. https://doi.org/10.3390/foods10102452

[PORIM] Palm Oil Refiners Association of Malaysia. (1995). PORIM Test Methods: Carotene Content.

Prättälä, R., Levälahti, E., Lallukka, T., Männistö, S., Paalanen, L., Raulio, S., Roos, E., Suominen, S., & Mäki-opas, T. (2015). From margarine to butter: Predictors of changing bread spread in an 11-year population follow-up. Public Health Nutrition, 19(9), 1707–1717. https://doi.org/10.1017/S1368980015003390

Rachmawati, A. N. (2022). Pengembangan produk oles kaya provitamin A berbasis oleogel minyak sawit merah [Skripsi]. Bogor: Fakultas Teknologi Pertanian, Institut Pertanian Bogor.

Rakprasoot, J., Tiampakdee, A., & Raviyan, P. (2023). Processing of red palm oil by modified acid degumming method. Food and Agriculture Sciences and Technology, 9(2), 11–22.

Rege, S. A., Momin, S. A., Wadekar, S. D., & Bhowmick, D. N. (2013). Formulation of a functional fat spread stabilized by natural antioxidants and emulsifiers. Malaysian Journal of Nutrition, 19(2), 121–130.

Ribeiro, J. A. A., Almeida, E. S., Neto, B. A. D., Abdelnur, P. V., & Monteiro, S. (2018). Identification of carotenoid isomers in crude and bleached palm oils by mass spectrometry. Food Science and Technology, 89, 631–637. https://doi.org/10.1016/j.lwt.2017.11.039

Samateh, M., Sagari, S., & John, G. (2018). Molecular oleogels: Green approach in structuring vegetable oils. In Edible oleogels (pp. 415–438). American Oil Chemists' Society Press.

dos Santos, M., Gerbaud, V., & le Roux, G. A. C. (2014). Solid fat content of vegetable oils and simulation of interesterification reaction: Predictions from thermodynamic approach. Journal of Food Engineering, 126, 198–205. https://doi.org/10.1016/j.jfoodeng.2013.11.012

Sarah, M. (2018). Carotenoids preservation during sterilization of palm fruit using microwave irradiation. Journal of Engineering and Applied Sciences, 13(3), 1009–1014.

Shabrina, & Broto, S. T. D. W. (2023). Optimization extraction of sunflower seed oil (Helianthus annuus) using factorial design experiment with soxhlation method. Journal of Vocational Studies on Applied Research, 5(1), 1–4.

Stevens, G. A., Bennett, J. E., Hennocq, Q., Lu, Y., De-Regil, L. M., Rogers, L., Danaei, G., & Li, G. (2015). Trends and mortality effects of vitamin A deficiency in children in 138 low-income and middle-income countries between 1991 and 2013: A pooled analysis of population-based surveys. The Lancet Global Health, 3(8), 528–536. https://doi.org/10.1016/S2214-109X(15)00039-X

Stutz, H., Bresgen, N., & Eckl, P. M. (2015). Analytical tools for the analysis of β-carotene and its degradation products. Free Radical Research, 49(6), 650–680. https://doi.org/10.3109/10715762.2015.1022539

Suriaini, N., Arpi, N., Syamsuddin, Y., & Supardan, M. D. (2023). Characteristics of palm oil-based oleogel and its potency as a shortening replacer. South African Journal of Chemical Engineering, 43, 197–203. https://doi.org/10.1016/j.sajce. 2022.11.003

[USDA] United States Department of Agriculture. (2023). Palm oil explorer. https://ipad.fas.usda.gov/cropexplorer/cropview/commodityView.aspx?cropid=4243000 [16 November 2023].

Wang, X., Wang, S., Nan, Y., & Liu, G. (2021). Production of margarines rich in unsaturated fatty acids using oxidative-stable vitamin C-loaded oleogel. Journal of Oleo Science, 70(10), 1059–1068. https://doi.org/10.5650/jos.ess20264

Wendt, A., Abraham, K., Wernecke, C., & Pfeiffer, J. F. E. (2018). Application of β-sitosterol + γ-oryzanol-structured organogel as migration barrier in filled chocolate products. Journal of the American Oil Chemists' Society, 94(9), 1131–1140. https://doi.org/10.1007/s11746-017-3024-9

Yilmaz, E., & Ogutcu, M. (2015). Oleogels as spreadable fat and butter alternatives: Sensory description and consumer perception. RSC Advances, 5(62), 50259–50267. https://doi.org/10.1039/C5RA06689A

Zaini, N. S. M., Mansor, N., Yusoff, M. M., & Rahim, M. H. A. (2023). Physico-chemical and sensory properties of red palm oil-based ice cream using maltodextrin or modified starch as stabilizers. Journal of Oleo Science, 9(11), 811–818. https://doi.org/10.5650/jos.ess23036

Ziarno, M., Derewiaka, D., Florowska, A., & Szymańska, I. (2023). Comparison of the spreadability of butter and butter substitutes. Applied Sciences, 13(4), 1–24. https://doi.org/10.3390/app13042600

Zbikowska, A., Onacik-Gür, S., Kowalska, M., Sowinski, M., Szymanska, I., Zbikowska, K., Marciniak-Łukasiak, K., & Werpachowski, W. (2022). Analysis of stability, rheological and structural properties of oleogels obtained from peanut oil structured with yellow beeswax. Gels, 8(7), 1–8. https://doi.org/10.3390/gels8070448

Authors

Annisa Noor Rachmawati
Nur Wulandari
wulandari_n@apps.ipb.ac.id (Primary Contact)
Eko Hari Purnomo
RachmawatiA. N., WulandariN., & PurnomoE. H. (2024). Pengembangan Produk Olesan Menggunakan Oleogel Minyak Sawit Merah sebagai Pensubstitusi Lemak Padat. Jurnal Teknologi Dan Industri Pangan, 35(2), 139-151. https://doi.org/10.6066/jtip.2024.35.2.139

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