Aplikasi kleinano dari tuf volkan Gunung Salak Indonesia sebagai adsorben alami kontaminan anionik: Fosfat perairan
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Accepted
22 December 2019
Published
1 January 2020
Abstract
Indonesia is rich with volcanic tuff-derived Andisols that contain variable charged minerals. This research was aimed at to extract nanoclays (diameter <200 nm) from volcanic tuffs, and to evaluate their potential as natural adsorbent of phosphate as contaminant in waters. Volcanic tuffs were taken from the 3rd (tv3) and 4th(tv4) layers of an Andisol profile at the foot slope of Salak Mountain Indonesia using dispersion-ultrasonication-centrifugation-dialysis separation procedure. By dispersing the materials in an acid condition (pH 4.0) followed with ultrasonication, it could be separated positively-charged nanoclays (nc3 and nc4) from the negative ones. The separated nanoclays were then purified using centrifugation and membrane dialysis techniques. Potential of the extracted nanoclays as natural phosphate adsorbent was evaluated by characterizing their adsorption maxima (b values) according to the Langmuir isothermal adsorption model. It could be extracted 2.82 mg nc3/g tv3 and 4.29 mg nc4/g tv4. The b values of nc3 at 12, 24, and 48 hours equilibration time (76.48, 92.10, and 117.54 mg P/g nc3) were higher than those of nc4 (50.17, 59.52, and 71.99 mg P/g nc4). The most effective equilibration-time was 48 hours. The extracted nanoclays were considered prospective as natural adsorbent for removal phosphate contaminant in waters
References
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Anwar S, Sudadi U. 2013. Kimia Tanah. Bogor: Institut Pertanian Bogor.
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He H, Barr TL, Klinowski J. 1995. ESCA and solid-state NMR studies of allophane. Clay Minerals. 30:201-209.
Henmi T, Wada K. 1976. Morphology and composition of allophane. American Mineralogist. 61:379-390.
Kaufold SD, Abidin Z, Henmi T, Matsue N, Eichinger L, Kaufold A, Jahn R. 2010. Allophane compared with other sorbent minerals for the removal of fluoride from water with particular focus on a mineable Ecuadorian allophane. Appl Clay Sci. 50:25-33.
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Murphy J, Riley JP. 1962. A modified single solution method for the determination of phosphate in natural waters. Analytica Chimica Acta. 27:31-36.
Padilla GN, Matsue N, Henmi T. 2002. Adsorption of sulfate and nitrate on nano-ball allophane. Clay Sci. 11:575-584.
Shukla EA, Johan E, Abidin ZA, Henmi T, Matsue N. 2013. A comparative study of arsenate and phosphate adsorption on nano-ball allophane. Clay Sci. 17:83-91.
Sudadi U, Wijaya H. 2012. Water-phosphorus sorption on nano-fraction extracted from volcanic tuff of Mt. Salak, West Java, Indonesia. Paper presented at the Regional Workshop on Water, Land, and Southeast Asia Food Sovereignty. Department of Soil Science and Land Resource, Faculty of Agriculture, Bogor Agricultural University in collaboration with Exceed, DAAD, and Federal Ministry for Economic Cooperation and Development, Germany. 18-19 September 2012. IPB International Convention Center, Bogor, Indonesia.
Tan KH. 1965. The andosol in Indonesia. Soil Sci. 375-378.
Theng BKG, Yuan G. 2008. Nanoparticles in the soil environment. Elements. 4:295-399.
Van Ranst E, Utami SR, Shamshuddin J. 2002. Andisols on volcanic ash from Java Island, Indonesia: Physico-chemical properties and classification. Soil Sci. 167(1):68-79.
Wada K, Wilson M, Kakuto Y, Wada SI, 1988. Synthesis and characterization of a hollow spherical form of monolayer aluminosilicate. Clays Clay Miner. 36:11-18.
Wada K. 1967. A structural scheme of soil allophane. Amer Mineralogist. 52:690-708.
Yuan G, Wu L. 2007. Allophane nanoclay for the removal of phosphorus in water and wastewater. Sci Tech Adv Material. 8:60-62.
Abidin Z, Matsue N, Henmi T. 2005. Molecular orbital analysis on the dissolution of nano-ball allophane under alkaline condition. Clay Sci. 13:1-6.
Abidin Z, Matsue N, Henmi T. 2007. Nanometer-scale chemical modification of nanoball allophane. Clays Clay Miner. 55:443-449.
Anwar S, Sudadi U. 2013. Kimia Tanah. Bogor: Institut Pertanian Bogor.
Bohn HL, McNeal BL, O’Connor GA. 1979. Soil Chemistry. New York: John Willey and Sons.
Calabi-floody M, Bendall JS, Jara AA, Welland ME, Theng BKG, Rumpel C, Mora ML. 2011. Nanoclays from an Andisol: Extraction, properties and carbon stabilization. Geoderma. 161:159-167.
Calabi-floody M, Theng BKG, Preyes P, Mora ML. 2009. Natural nanoclays: applications and future trends – a Chilean perspective. Clay Minerals. 44:161-176.
Carpenter SR, Caraco NF, Correle DL, Howarth RW, Sharpley AN, Smith VH. 1998. Nonpoint pollution of surface waters with phosphorus and nitrogen. Ecological Applications. 8(3):559-568.
Ghoneim A, Matsue N, Henmi T. 2006. Effect of copper adsorption on some charge characteristics of nano-ball allophane. Intern J Soil Sci. 1(3):243-250.
He H, Barr TL, Klinowski J. 1995. ESCA and solid-state NMR studies of allophane. Clay Minerals. 30:201-209.
Henmi T, Wada K. 1976. Morphology and composition of allophane. American Mineralogist. 61:379-390.
Kaufold SD, Abidin Z, Henmi T, Matsue N, Eichinger L, Kaufold A, Jahn R. 2010. Allophane compared with other sorbent minerals for the removal of fluoride from water with particular focus on a mineable Ecuadorian allophane. Appl Clay Sci. 50:25-33.
Leamy ML, Kinloch DI, Parfitt RL. 1990. International Committee on Andisols: Final Report. Technical Monograph No. 20. Soil Management Support Services, Washington DC.
Murphy J, Riley JP. 1962. A modified single solution method for the determination of phosphate in natural waters. Analytica Chimica Acta. 27:31-36.
Padilla GN, Matsue N, Henmi T. 2002. Adsorption of sulfate and nitrate on nano-ball allophane. Clay Sci. 11:575-584.
Shukla EA, Johan E, Abidin ZA, Henmi T, Matsue N. 2013. A comparative study of arsenate and phosphate adsorption on nano-ball allophane. Clay Sci. 17:83-91.
Sudadi U, Wijaya H. 2012. Water-phosphorus sorption on nano-fraction extracted from volcanic tuff of Mt. Salak, West Java, Indonesia. Paper presented at the Regional Workshop on Water, Land, and Southeast Asia Food Sovereignty. Department of Soil Science and Land Resource, Faculty of Agriculture, Bogor Agricultural University in collaboration with Exceed, DAAD, and Federal Ministry for Economic Cooperation and Development, Germany. 18-19 September 2012. IPB International Convention Center, Bogor, Indonesia.
Tan KH. 1965. The andosol in Indonesia. Soil Sci. 375-378.
Theng BKG, Yuan G. 2008. Nanoparticles in the soil environment. Elements. 4:295-399.
Van Ranst E, Utami SR, Shamshuddin J. 2002. Andisols on volcanic ash from Java Island, Indonesia: Physico-chemical properties and classification. Soil Sci. 167(1):68-79.
Wada K, Wilson M, Kakuto Y, Wada SI, 1988. Synthesis and characterization of a hollow spherical form of monolayer aluminosilicate. Clays Clay Miner. 36:11-18.
Wada K. 1967. A structural scheme of soil allophane. Amer Mineralogist. 52:690-708.
Yuan G, Wu L. 2007. Allophane nanoclay for the removal of phosphorus in water and wastewater. Sci Tech Adv Material. 8:60-62.
Authors
SudadiU., AnggriawanR. and AnwarS. (2020) “Aplikasi kleinano dari tuf volkan Gunung Salak Indonesia sebagai adsorben alami kontaminan anionik: Fosfat perairan”, Jurnal Pengelolaan Sumberdaya Alam dan Lingkungan (Journal of Natural Resources and Environmental Management). Bogor, ID, 9(4), pp. 1032-1040. doi: 10.29244/jpsl.9.4.1032-1040.
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