Sintesis Komposit Zeolit X/Oksida Perak dan Tembaga Melalui Reaksi Tollens Serta Aplikasinya Sebagai Adsorben:

Hasanuddin Rizal; Zaenal Abidin; Trivadila; Nurul Hiedayati

doi:10.29244/jitl.24.2.87-95

Hasanuddin Rizal Departemen Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, IPB University
Zaenal Abidin Department of Chemistry, Fac. of Math and Natural Sciences, IPB University
Trivadila Departemen Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, IPB University
Nurul Hiedayati Departemen Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, IPB University

DOI: https://doi.org/10.29244/jitl.24.2.87-95

Keywords: adsorbent, composite, copper, silver, zeolite

Abstract

Zeolite is a micro porous aluminosilic mineral that has a wide surface. Its wide surface causes zeolite to be commonly used as an adsorbent. Zeolite X is included in the Faujasite structure and usually binds sodium cations. Cations bound to zeolites can be exchanged for other cations, such as transition metal cations. Transition metal cations such as [Ag(NH3)2]⁺are commonly used to detect aldehyde groups or commonly known as Tollens reagents. This study aims to synthesize composite adsorbent zeolite X / silver oxide and zeolite X / copper oxide through Tollens reaction. Composites characterized using scanning electron microscope showed that the composite surface was coarser than the surface of zeolite X. The material used as a model for adsorption was ammonia gas. The resulting composites are of three types based on the stages of zeolite addition in the synthesis process, namely after the addition of a precursor (composite 1), after addition of NH₄OH (composite 2), and after heating (composite 3). The resulting composite can increase the adsorption of ammonia by up to 2 times than zeolite X.

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Synthesis Zeolite X/Silver and Copper Oxide Composite via Tollens Reactions and Its Application as Adsorbent